Project period: 2022 - 2023
Contact: Dr. Anke Neumann Jenal
Clay minerals are ubiquitous in sediments and soils and have long been regarded as mostly unreactive but are emerging as potentially important redox-active minerals in natural environments. Intriguingly, their interaction with the naturally abundant reductant ferrous iron leads to the formation of transient, yet highly reactive mineral species capable of degrading recalcitrant contaminants. We suspect that the mineral identity and crystallinity of these mineral species is key to the reactivity observed and hence to understanding their role in many of Earth’s crucial element cycles, as well as nutrient availability, and contaminant degradation.
The target minerals are likely amorphous or nano-crystalline, present in low abundance and most often made up of particles of very small sizes (nanometer range). Thus, facilities and analytical tools that cannot just identify but fully characterize these nanophases are needed. At GFZ, high-resolution transmission electron microscopy (HR-TEM) and atomic pair distribution function (PDF) method will be used and complemented with Mössbauer spectroscopy at Newcastle University. Insights from this project will improve our understanding of how clay mineral redox reactions control the identity and reactivity of reactive mineral intermediates and, hence, how clay minerals control redox reactions on Earth.
Project period: 2021 - 2023
Contact: Dr. Elizaveta Kovaleva
The research project aims at understanding the impact cratering process, its conditions and effects, by constraining the pressure-temperature (P-T) phase diagrams (geo-thermobarometry) and geochronological studies (age dating) for accessory minerals that experienced shock deformation. The project will be realized via search and identification of the new shock microstructures in accessory minerals; study of known shock microstructures in accessory minerals (microtwins, planar fractures, neoblastic granular textures, inclusions of high-pressure polymorphs), and determining their formation mechanisms and the age of shock deformation. Besides, I will study the spatial distribution of shocked minerals within the target rocks relative to the crater center and the shock-induced melt bodies within the impact structure; conduct the estimation and calibration of the shock pressures throughout the crater with in situ studies of shocked minerals; correlate shock microstructures found in different minerals and various types of impactites from different impact craters.
Publikationen
Kovaleva, E., Helmy, H., Belkacim, S., Schreiber, A., Wilke, F. & Wirth, R. (2023): Libyan Desert Glass: New evidence for an extremely high-pressure-temperature impact event from nanostructural study. - American Mineralogist, 108(10), 1906-1923. https://doi.org/10.2138/am-2022-8759
Kusiak, M., Kovaleva, E., Vanderliek, D., Becker, H., Wilke, F., Schreiber, A., Wirth, R. (2022): Nano- and micro-structures in lunar zircon from Apollo 15 and 16 impactites: implications for age interpretations. - Contributions to Mineralogy and Petrology, 177, 112.
https://doi.org/10.1007/s00410-022-01977-8
Kovaleva, E., Kusiak, M. A., Kenny, G. G., Whitehouse, M. J., Habler, G., Schreiber, A., Wirth, R. (2021): Nano-scale investigation of granular neoblastic zircon, Vredefort impact structure, South Africa: Evidence for complete shock melting. - Earth and Planetary Science Letters, 565, 116948.
https://doi.org/10.1016/j.epsl.2021.116948
Project period: 2021 - 2023
Contact: Dr. Runa Antony
Light absorbing organic matter, together with mineral dust and pigmented microbes, massively reduce the snow and ice surface albedo (amount of solar energy reflected from the ice surface). This leads to increased solar radiation absorption, resulting in accelerated melting of the ice sheet surface.
I aim to derive a quantitative and qualitative understanding of the nature, sources, on-ice microbial processing and fluxes of organic matter on the ever-changing ice surface during melting. This way I hope to provide novel, holistic insights on the interplay between microbial metabolism, carbon cycling and surface melting and help fine tune the response of Greenland’s ice masses to future climate warming scenarios in global predictive models.
Project period: 2019 - 2021
Contact: Dr. James Bradley
The Greenland lce Sheet Surface (GrISS) hosts diverse communities of microorganisms and algae whose activity controls transfers and transformations of carbon and nutrients, and albedo (and thus melting). A numerical tool to capture the biological and biogeochemical processes on ice surfaces currently does not exist, and thus a fully mechanistic understanding of these processes is lacking. Without this tool, quantifying and predicting past, present and future GrISS biogeochemical processes and their associated global feedbacks is impossible. I will address this key knowledge gap by developing and implementing a new modelling tool used to simulate biogeochemical processes on the GrISS and the susceptibility of these processes to climate change. The model will also guide future experimental efforts and act as a cross-disciplinary knowledge-sharing platform. This fellowship will provide me with the means to become an expert in developing, applying and integrating numerical and experimental techniques and benefit my future career.